Because fat is "stickier," it tends to be expressed later on in a nursing or pumping session. Therefore, foremilk tends to be more watery and hindmilk tends to be fattier.
Some babies may get too much watery milk and not enough hindmilk, which is called foremilk/ hindmilk imbalance. It's far more common when nursing (due to switching sides too often) than exclusive pumping.
If you are worried about foremilk/ hindmilk imbalance, look at your BABY rather than your milk. If baby is happy and growing well, a thin layer of fat on your separated milk is very likely not an issue.